5-Bromo-3-(4-fluorophenylsulfonyl)-2,7-dimethyl-1-benzofuran
نویسندگان
چکیده
In the title compound, C(16)H(12)BrFO(3)S, the 4-fluoro-phenyl ring makes a dihedral angle of 72.35 (5)° with the mean plane [r.m.s. deviation = 0.008 (1) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked into [010] chains via two different inversion-generated pairs of C-H⋯O hydrogen bonds. The crystal structure also exhibits slipped π-π inter-actions between the benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.667 (2) Å and slippage = 1.341 (2) Å], and between the benzene and the furan rings of neighbouring mol-ecules [centroid-centroid distance = 3.759 (2) Å and slippage = 0.757 (2) Å].
منابع مشابه
3-(4-Fluorophenylsulfonyl)-5-iodo-2,7-dimethyl-1-benzofuran
In the title compound, C(16)H(12)FIO(3)S, the 4-fluoro-phenyl ring makes a dihedral angle of 72.31 (6)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds, and by an I⋯I contact [3.7764 (3) Å]. The crystal structure also exhibits a weak C-I⋯π [3.901 (3) Å] inter-action and a slipped π-π inter-action between the furan and benzene ri...
متن کامل5-Bromo-3-(4-fluorophenylsulfinyl)-2,7-dimethyl-1-benzofuran
In the title compound, C(16)H(12)BrFO(2)S, the 4-fluoro-phenyl ring makes a dihedral angle of 83.29 (5)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked by weak inter-molecular C-H⋯O hydrogen bonds.
متن کامل5-Bromo-3-cyclohexylsulfonyl-2,7-dimethyl-1-benzofuran
In the title compound, C(16)H(19)BrO(3)S, the cyclo-hexyl ring adopts a chair conformation. In the crystal, mol-ecules are linked through weak C-H⋯O hydrogen bonds and Br⋯O contacts [3.211 (1) Å].
متن کامل5-Bromo-3-(4-fluorophenylsulfonyl)-2-methyl-1-benzofuran
In the title compound, C(15)H(10)BrFO(3)S, the 4-fluoro-phenyl ring makes a dihedral angle of 76.51 (6)° with the plane of the benzofuran fragment. In the crystal, mol-ecules are linked by weak non-classical inter-molecular C-H⋯O hydrogen bonds and an aromatic π-π inter-action between the benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.540 (3) Å].
متن کامل5-Bromo-3-cyclohexylsulfinyl-2,7-dimethyl-1-benzofuran
In the title compound, C(16)H(19)BrO(2)S, the cyclo-hexyl ring adopts a chair conformation. In the crystal, mol-ecules are linked by a Br⋯Br [3.5994 (5) Å] contact and a C-H⋯π inter-action involving the phenyl ring of the benzofuran. The crystal structure also exhibits a slipped π-π inter-action between the furan rings of neighbouring mol-ecules [centroid-centroid distance = 3.767 (1) Å and int...
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